Loads to see in Sydney. Public Transport is very good.
The Opera House. The Rocks, The Bridge Climb, Walking in The Botanical Gardens, The Aquarium in Darling Harbour, take a harbour cruise, Taronga Zoo (take a ferry ride there) The shops(especially the Queen Victoria Bldg) The cafés and restaurants. Bondi Beach though I preferred Manly Beach, The Blue Mountains you can get a train out there or take a tour, and loads more.
A good guide book is the AA City Pack on Sydney. It has a good map and loads of info about what to see so that you can plan your sightseeing before arrival.