Hi if you google lan chile seats the first selection is concerning the pacific islands on that site is the seat map for the 767-300 and the last row is row 38. However this is only showing 3 class configuration and Lan Chile do have 4 classes now on some planes, so this picture may be out of date.
As for Lan Chile, I flew Auckland to Santiago on an A340 in 2003 and they were great, food was ok, no problems